ODF bottle data along with US GEOTRACES North Atlantic Transect from the R/V Knorr KN199-04 cruise in the subtropical N. Atlantic during 2010 (U.S. GEOTRACES NAT project)

Website: https://www.bco-dmo.org/dataset/3519
Data Type: Cruise Results
Version: 4
Version Date: 2013-02-13

Project
» U.S. GEOTRACES North Atlantic Transect (GA03) (U.S. GEOTRACES NAT)

Program
» U.S. GEOTRACES (U.S. GEOTRACES)
ContributorsAffiliationRole
Jenkins, William J.Woods Hole Oceanographic Institution (WHOI)Principal Investigator, Contact
Boyle, Edward A.Massachusetts Institute of Technology (MIT)Co-Principal Investigator
Cutter, Gregory A.Old Dominion University (ODU)Co-Principal Investigator
Gegg, Stephen R.Woods Hole Oceanographic Institution (WHOI BCO-DMO)BCO-DMO Data Manager

Abstract
ODF bottle data along with US GEOTRACES North Atlantic Transect from the R/V Knorr KN199-04 cruise in the subtropical N. Atlantic during 2010.


Coverage

Spatial Extent: N:38.3334 E:-9.66 S:17.3497 W:-24.5329
Temporal Extent: 2010-10-16 - 2010-11-03

Dataset Description

CTD bottle data from 30-ODF/SIOR (Ocean Data Facility 12 bottle, 30 liter Niskin rosette) GT10 Transect.

 


Methods & Sampling

"Filtered samples for non-contamination prone elements were collected from the ODF Niskin rosette (12 x 30L Niskin bottles) using AcroPak 500 filter cartridges with a Supor 0.45/0.8μm membrane attached to Teflon-lined Tygon tubing." (from KN199-04 cruise report). Refer to th KN199-04 Cruise Report for detailed descriptions of acquisition and processing methodologies.


Data Processing Description

Refer to th KN199-04 Cruise Report for detailed descriptions of acquisition and processing methodologies.

Note: 'FLAG_W' columns = WHP (WOCE Hydrographic Program) quality flags.

Processing Notes:
13 Feb 2013: BCO-DMO corrected the event numbers of several CTD casts. The correct event numbers were verified in the original cast sheets. Edits made:
Changed event number of station 2 cast 1 from 2022 to 2042;
Changed event number of station 4 cast 1 from 2024 to 2072;
Changed event number of station 5 cast 4 from 2075 to 2091;
Changed event number of station 7 cast 6 from 2107 to 2132;
Changed event number of station 9 cast 1 from 2009 to 2162;
Changed event number of station 9 cast 3 from 2059 to 2165.

The restriction on this dataset was removed according to instructions from the Chief Scientist, April 26, 2013.


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Data Files

File
CTD_ODF_Bottle_GT10.csv
(Comma Separated Values (.csv), 298.79 KB)
MD5:833243cd24f03e42ec7d02bcde781789
Primary data file for dataset ID 3519

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Parameters

ParameterDescriptionUnits
EXPOCODE

Expedition code assigned by the CCHDO: NODCShipCodeYearMonthDay

text
SECT_ID

Synonym for cruise.

text
STNNBR

Station number.

integer
CASTNO

Cast number.

integer
GEOTRC_EVENTNO

GEOTRACES Event Number.

integer
DATE

Date (UTC). in the format YYYYMMDD

unitless
TIME

Time (UTC). in the format HHMM

unitless
LATITUDE

Latitude (South is negative).

decimal degrees
LONGITUDE

Longitude (West is negative).

decimal degrees
GEOTRC_SAMPNO

GEOTRACES sample number.

integer
SAMPNO

Sample number.

integer
BTLNBR

Bottle identification number.

text
BTLNBR_FLAT_W

Bottle quality flag.

integer
BTO_DATE

Bottle sampling date. in the format YYYYMMDD

unitless
BTL_TIME

Bottle collection time. in the format HHMM

unitless
BTL_LAT

Bottle latitude (South is negative).

decimal degrees
BTL_LON

Bottle longitude (West is negative).

decimal degrees
BTMDEPTH

Bottom depth.

meters, corrected
CTDPRS

CTD pressure.

decibars
CTDDEPTH

CTD depth.

meters
CTDTMP

CTD temperature.

ITS-90
CTDSAL

CTD salinity.

PSS-78
CTDSAL_FLAG_W

Quality flag for CTDSAL.

integer
SALNTY

Bottle salinity.

PSS-78
SALNTY_FLAG_W

Quality flag for SALINITY.

integer
CTDOXY

CTD Oxygen in micromoles per kilogram.

umol/kg
CTDOXY_FLAG_W

Quality flag for CTDOXY.

integer
OXYGEN

Bottle oxygen measured in micromoles per kilogram.

umol/kg
OXYGEN_FLAG_W

OXYGEN FLAG W

integer
SILCAT

Silicate.

umol/kg
SILCAT_FLAG_W

Quality flag for SILCAT.

integer
NITRAT

Nitrate.

umol/kg
NITRAT_FLAG_W

Quality flag for NITRAT.

integer
NITRIT

Nitirite.

umol/kg
NITRIT_FLAG_W

Quality flag for NITRIT.

integer
PHSPHT

Phosphate.

umol/kg
PHSPHT_FLAG_W

Quality flag for PHSPHT.

integer
REFTEMP

REFTEMP

ITS-90
REFTEMP_FLAG_W

REFTEMP FLAG W

integer
CFC_11

CFC 11 (trichlorofluoromethane) in picomoles per kilogram.

pmol/kg
CFC_11_FLAG_W

Quality flag for CFC_11.

integer
CFC_12

CFC 12 (Dichlorodifluoromethane) in picomoles per kilogram.

pmol/kg
CFC_12_FLAG_W

Quality flag for CFC_12.

integer
CFC113

CFC-113 (Trichlorotrifluoroethane) in picomoles per kilogram.

pmol/kg
CFC113_FLAG_W

Quality flag for CFC113.

integer
SF6

SF6 (Sulfur hexafluoride) in fmol per kilogram.

fmol/kg
SF6_FLAG_W

Quality flag for SF6.

integer
TCARBN_M

TCARBN M

UMOL/KG
TCARBN_M_FLAG_W

TCARBN M FLAG W

integer
ALKALI_M

ALKALI M

UMOL/KG
ALKALI_M_FLAG_W

ALKALI M FLAG W

integer
TCARBN_B

TCARBN B

UMOL/KG
TCARBN_B_FLAG_W

TCARBN B FLAG W

integer
ALKALI_B

ALKALI B

UMOL/KG
ALKALI_B_FLAG_W

ALKALI B FLAG W

integer
TRITUM

Tritium.

TU
TRITUM_FLAG_W

Quality flag for TRITUM.

integer
HELIUM

Helium.

nmol/kg
HELIUM_FLAG_W

Quality flag for HELIUM.

integer
DELHE3

Helium isotope ratio anomaly (percentage).

%
DELHE3_FLAG_W

Quality flag for DELHE3.

integer
DELC13

DELC13

/MILLE
DELC13_FLAG_W

Quality flag for DELC13.

integer
DELC14

DELC14

/MILLE
DELC14_FLAG_W

Quality flag for DELC14.

integer
D15N_NO3

D15N NO3

/MILLEvsAIR
D15N_NO3_FLAG_W

D15N NO3 FLAG W

integer
D18O_NO3

D18O NO3

/MILLEvsVSMOW
D18O_NO3_FLAG_W

D18O NO3 FLAG W

integer
O18_H2O

18O H2O

/MILLE
O18_H2O_FLAG_W

18O H2O FLAG W

integer
SI_SW_DISS

SI SW DISS

/MILLE
SI_SW_DISS_FLAG_W

SI SW DISS FLAG W

integer
SI_PM

SI PM

/MILLE
SI_PM_FLAG_W

SI PM FLAG W

integer
TCHLA

TCHLA

UG/L
TCHLA_FLAG_W

TCHLA FLAG W

integer
ACDOM

ACDOM

1/M
ACDOM_FLAG_W

ACDOM FLAG W

integer
AP

AP

1/M^2
AP_FLAG_W

AP FLAG W

integer
DOC

Dissolved Organic Carbon in micromoles per liter.

UMOL/L
DOC_FLAG_W

Quality flag for DOC.

integer
POC

Particulate Organic Carbon in micrograms per liter.

ug/L
POC_FLAG_W

Quality flag for POC.

integer
SPM

SPM

UG/L
SPM_FLAG_W

SPM FLAG W

integer
HPLC_PIGMENTS

HPLC PIGMENTS

UG/L
HPLC_PIGMENTS_FLAG_W

HPLC PIGMENTS FLAG W

integer
CYSTEINE

CYSTEINE

PMOL/L
CYSTEINE_FLAG_W

CYSTEINE FLAG W

integer
GLUTATHIONE

GLUTATHIONE

PMOL/L
GLUTATHIONE_FLAG_W

GLUTATHIONE FLAG W

integer
GAMMA_GLU_CYST

GAMMA GLU CYST

PMOL/L
GAMMA_GLU_CYST_FLAG_W

GAMMA GLU CYST FLAG W

integer
HOMOCYSTEINE

HOMOCYSTEINE

PMOL/L
HOMOCYSTEINE_FLAG_W

HOMOCYSTEINE FLAG W

integer
PHYTOCHELATINS

PHYTOCHELATINS

PMOL/L
PHYTOCHELATINS_FLAG_W

PHYTOCHELATINS FLAG W

integer
METALLOTHEIONINE

METALLOTHEIONINE

PMOL/L
METALLOTHEIONINE_FLAG_W

METALLOTHEIONINE FLAG W

integer
DNA_CHISHOLM

DNA CHISHOLM

TBA
DNA_CHISHOLM_FLAG_W

DNA CHISHOLM FLAG W

integer
DNA_LAROCHE

DNA LAROCHE

TBA
DNA_LAROCHE_FLAG_W

DNA LAROCHE FLAG W

integer
BA

BA

NMOL/L
BA_FLAG_W

BA FLAG W

integer
ND_143_to_ND_144

ND-143/ND-144

RATIO
ND_143_to_ND_144_FLAG_W

ND-143/ND-144 FLAG W

integer
EPSILON_ND

EPSILON ND

(tbd)
EPSILON_ND_FLAG_W

EPSILON ND FLAG W

integer
PO_210

PO 210

DPM/100L
PO_210_FLAG_W

PO 210 FLAG W

integer
PB_210

Pb-210 (Lead-210).

DPM/100L
PB_210_FLAG_W

Quality flag for PB_210.

integer
RA_226

Radium-226 disintegrations per minute per 100 liters.

DPM/100L
RA_226_FLAG_W

Quality flag for RA_226.

integer
TH_230

Thorium-230.

fg/kg
TH_230_FLAG_W

Quality flag for TH_230.

integer
TH_232

Thorium-232.

pg/kg
TH_232_FLAG_W

Quality flag for TH_232.

integer
TH_232_COLLOIDS

TH 232 COLLOIDS

PG/KG
TH_232_COLLOIDS_FLAG_W

TH 232 COLLOIDS FLAG W

integer
TH_234

Thorium-234.

DPM/L
TH_234_FLAG_W

Quality flag for Th_234.

integer
PA_231

PA 231

FG/KG
PA_231_FLAG_W

PA 231 FLAG W

integer
U_238

Uranium-238.

TBA
U_238_FLAG_W

Quality flag for U_238.

integer
CS_137

Caesium-137 in becquerels per cubic meter.

BQ/M^3
CS_137_FLAG_W

Quality flag for CS_137.

integer
NP_237

Neptunium-237.

MBQ/M^3
NP_237_FLAG_W

Quality flag for NP_237.

integer
PU_239

Plutonium-239.

MBQ/M^3
PU_239_FLAG_W

Quality flag for PU_239.

integer
PU_240

Plutonium-240.

MBQ/M^3
PU_240_FLAG_W

Quality flag for PU_240.

integer
PU_240_to_PU_239

PU-240/PU-239

RATIO
PU_240_to_PU_239_FLAG_W

PU-240/PU-239 FLAG W

integer
REE_LA_UH

REE (Rare Earth Element) Lanthanum reported by University of Hawaii.

PMOL/KG
REE_LA_UH_FLAG_W

Quality flag for REE_LA_UH.

integer
REE_CE_UH

REE (Rare Earth Element) Cerium reported by University of Hawaii.

PMOL/KG
REE_CE_UH_FLAG_W

Quality flag for REE_CE_UH.

integer
REE_PR_UH

REE (Rare Earth Element) Praseodymium reported by University of Hawaii.

PMOL/KG
REE_PR_UH_FLAG_W

Quality flag for REE_PR_UH.

integer
REE_ND_UH

REE (Rare Earth Element) Neodymium reported by University of Hawaii.

PMOL/KG
REE_ND_UH_FLAG_W

Quality flag for REE_ND_UH.

integer
REE_PM_UH

REE (Rare Earth Element) Promethium reported by University of Hawaii.

PMOL/KG
REE_PM_UH_FLAG_W

Quality flag for REE_PM_UH.

integer
REE_SM_UH

REE (Rare Earth Element) Samarium reported by University of Hawaii.

PMOL/KG
REE_SM_UH_FLAG_W

Quality flag for REE_SM_UH.

integer
REE_EU_UH

REE (Rare Earth Element) Europium reported by University of Hawaii.

PMOL/KG
REE_EU_UH_FLAG_W

Quality flag for REE_EU_UH.

integer
REE_GD_UH

REE (Rare Earth Element) Gadolinium reported by University of Hawaii.

PMOL/KG
REE_GD_UH_FLAG_W

Quality flag for REE_GD_UH.

integer
REE_TB_UH

REE (Rare Earth Element) Terbium reported by University of Hawaii.

PMOL/KG
REE_TB_UH_FLAG_W

Quality flag for REE_TB_UH.

integer
REE_DY_UH

REE (Rare Earth Element) Dysprosium reported by University of Hawaii.

PMOL/KG
REE_DY_UH_FLAG_W

Quality flag for REE_DY_UH.

integer
REE_HO_UH

REE (Rare Earth Element) Holmium reported by University of Hawaii.

PMOL/KG
REE_HO_UH_FLAG_W

Quality flag for REE_HO_UH.

integer
REE_ER_UH

REE (Rare Earth Element) Erbium reported by University of Hawaii.

PMOL/KG
REE_ER_UH_FLAG_W

Quality flag for REE_ER_UH.

integer
REE_TM_UH

REE (Rare Earth Element) Thulium reported by University of Hawaii.

PMOL/KG
REE_TM_UH_FLAG_W

Quality flag for REE_TM_UH.

integer
REE_YB_UH

REE (Rare Earth Elements) Ytterbium reported by University of Hawaii.

PMOL/KG
REE_YB_UH_FLAG_W

Quality flag for REE_YB_UH.

integer
REE_LU_UH

REE (Rare Earth Element) Lutetium reported by University of Hawaii.

PMOL/KG
REE_LU_UH_FLAG_W

Quality flag for REE_LU_UH.

integer


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Instruments

Dataset-specific Instrument Name
GO-FLO Bottle
Generic Instrument Name
GO-FLO Bottle
Generic Instrument Description
GO-FLO bottle cast used to collect water samples for pigment, nutrient, plankton, etc. The GO-FLO sampling bottle is specially designed to avoid sample contamination at the surface, internal spring contamination, loss of sample on deck (internal seals), and exchange of water from different depths.

Dataset-specific Instrument Name
Niskin bottle
Generic Instrument Name
Niskin bottle
Generic Instrument Description
A Niskin bottle (a next generation water sampler based on the Nansen bottle) is a cylindrical, non-metallic water collection device with stoppers at both ends. The bottles can be attached individually on a hydrowire or deployed in 12, 24, or 36 bottle Rosette systems mounted on a frame and combined with a CTD. Niskin bottles are used to collect discrete water samples for a range of measurements including pigments, nutrients, plankton, etc.


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Deployments

KN199-04

Website
Platform
R/V Knorr
Report
Start Date
2010-10-15
End Date
2010-11-04
Description
This cruise constitutes the first survey section as part of the U.S. participation in an international program named GEOTRACES. Funding: NSF OCE award 0926423 Science Objectives: To obtain state of the art trace metal and isotope measurements on a suite of samples taken on a mid-latitude zonal transect of the North Atlantic. In particular, sampling targeted the oxygen minimum zone extending off the west African coast near Mauritania, the TAG hydrothermal field, and the western boundary current system along Line W. For additional information, please refer to the GEOTRACES program Web site (https://www.geotraces.org/) for overall program objectives and a summary of properties measured. Science Activities include seawater sampling via GoFLO and Niskin carousels, in situ pumping (and filtration), CTDO2 and transmissometer sensors, underway pumped sampling of surface waters, and collection of aerosols and rain. Hydrography, CTD and nutrient measurements were supported by the Ocean Data Facility (J. Swift) at Scripps Institution of Oceanography and funded through NSF Facilities. They provided an additional CTD rosette system along with nephelometer and LADCP. A trace metal clean Go-Flo Rosette and winch were provided by the group at Old Dominion University (G. Cutter) along with a towed underway pumping system. Additional cruise information is available from the Rolling Deck to Repository (R2R): https://www.rvdata.us/search/cruise/KN199-04 Other Relevant Links: List of cruise participants: [ PDF ] Cruise track: JPEG image (from Woods Hole Oceanographic Institution, vessel operator) ADCP data are available from the Currents ADCP group at the University of Hawaii: KN199-04 ADCP


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Project Information

U.S. GEOTRACES North Atlantic Transect (GA03) (U.S. GEOTRACES NAT)


Coverage: Subtropical western and eastern North Atlantic Ocean (GA03)


Much of this text appeared in an article published in OCB News, October 2008, by the OCB Project Office.

The first U.S. GEOTRACES Atlantic Section will be specifically centered around a sampling cruise to be carried out in the North Atlantic in 2010. Ed Boyle (MIT) and Bill Jenkins (WHOI) organized a three-day planning workshop that was held September 22-24, 2008 at the Woods Hole Oceanographic Institution. The main goal of the workshop, sponsored by the National Science Foundation and the U.S. GEOTRACES Scientific Steering Committee, was to design the implementation plan for the first U.S. GEOTRACES Atlantic Section. The primary cruise design motivation was to improve knowledge of the sources, sinks and internal cycling of Trace Elements and their Isotopes (TEIs) by studying their distributions along a section in the North Atlantic (Figure 1). The North Atlantic has the full suite of processes that affect TEIs, including strong meridional advection, boundary scavenging and source effects, aeolian deposition, and the salty Mediterranean Outflow. The North Atlantic is particularly important as it lies at the "origin" of the global Meridional Overturning Circulation.

It is well understood that many trace metals play important roles in biogeochemical processes and the carbon cycle, yet very little is known about their large-scale distributions and the regional scale processes that affect them. Recent advances in sampling and analytical techniques, along with advances in our understanding of their roles in enzymatic and catalytic processes in the open ocean provide a natural opportunity to make substantial advances in our understanding of these important elements. Moreover, we are motivated by the prospect of global change and the need to understand the present and future workings of the ocean's biogeochemistry. The GEOTRACES strategy is to measure a broad suite of TEIs to constrain the critical biogeochemical processes that influence their distributions. In addition to these "exotic" substances, more traditional properties, including macronutrients (at micromolar and nanomolar levels), CTD, bio-optical parameters, and carbon system characteristics will be measured. The cruise starts at Line W, a repeat hydrographic section southeast of Cape Cod, extends to Bermuda and subsequently through the North Atlantic oligotrophic subtropical gyre, then transects into the African coast in the northern limb of the coastal upwelling region. From there, the cruise goes northward into the Mediterranean outflow. The station locations shown on the map are for the "fulldepth TEI" stations, and constitute approximately half of the stations to be ultimately occupied.

Figure 1. The proposed 2010 Atlantic GEOTRACES cruise track plotted on dissolved oxygen at 400 m depth. Data from the World Ocean Atlas (Levitus et al., 2005) were plotted using Ocean Data View (courtesy Reiner Schlitzer). [click on the image to view a larger version]

Hydrography, CTD and nutrient measurements will be supported by the Ocean Data Facility (J. Swift) at Scripps Institution of Oceanography and funded through NSF Facilities. They will be providing an additional CTD rosette system along with nephelometer and LADCP. A trace metal clean Go-Flo Rosette and winch will be provided by the group at Old Dominion University (G. Cutter) along with a towed underway pumping system.

The North Atlantic Transect cruise began in 2010 with KN199 leg 4 (station sampling) and leg 5 (underway sampling only) (Figure 2).

KN199-04 Cruise Report (PDF)

Figure 2. The red line shows the cruise track for the first leg of the US Geotraces North Atlantic Transect on the R/V Knorr in October 2010.  The rest of the stations (beginning with 13) will be completed in October-December 2011 on the R/V Knorr (courtesy of Bill Jenkins, Chief Scientist, GNAT first leg). [click on the image to view a larger version]
Atlantic Transect Station location map

The section completion effort resumed again in November 2011 with KN204-01A,B (Figure 3).

KN204-01A,B Cruise Report (PDF)

Figure 3. Station locations occupied on the US Geotraces North Atlantic Transect on the R/V Knorr in November 2011.  [click on the image to view a larger version]
Atlantic Transect/Part 2 Station location map

Data from the North Atlantic Transect cruises are available under the Datasets heading below, and consensus values for the SAFe and North Atlantic GEOTRACES Reference Seawater Samples are available from the GEOTRACES Program Office: Standards and Reference Materials

ADCP data are available from the Currents ADCP group at the University of Hawaii at the links below:
KN199-04   (leg 1 of 2010 cruise; Lisbon to Cape Verde)
KN199-05   (leg 2 of 2010 cruise; Cape Verde to Charleston, NC)
KN204-01A (part 1 of 2011 cruise; Woods Hole, MA to Bermuda)
KN204-01B (part 2 of 2011 cruise; Bermuda to Cape Verde)



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Program Information

U.S. GEOTRACES (U.S. GEOTRACES)


Coverage: Global


GEOTRACES is a SCOR sponsored program; and funding for program infrastructure development is provided by the U.S. National Science Foundation.

GEOTRACES gained momentum following a special symposium, S02: Biogeochemical cycling of trace elements and isotopes in the ocean and applications to constrain contemporary marine processes (GEOSECS II), at a 2003 Goldschmidt meeting convened in Japan. The GEOSECS II acronym referred to the Geochemical Ocean Section Studies To determine full water column distributions of selected trace elements and isotopes, including their concentration, chemical speciation, and physical form, along a sufficient number of sections in each ocean basin to establish the principal relationships between these distributions and with more traditional hydrographic parameters;

* To evaluate the sources, sinks, and internal cycling of these species and thereby characterize more completely the physical, chemical and biological processes regulating their distributions, and the sensitivity of these processes to global change; and

* To understand the processes that control the concentrations of geochemical species used for proxies of the past environment, both in the water column and in the substrates that reflect the water column.

GEOTRACES will be global in scope, consisting of ocean sections complemented by regional process studies. Sections and process studies will combine fieldwork, laboratory experiments and modelling. Beyond realizing the scientific objectives identified above, a natural outcome of this work will be to build a community of marine scientists who understand the processes regulating trace element cycles sufficiently well to exploit this knowledge reliably in future interdisciplinary studies.

Expand "Projects" below for information about and data resulting from individual US GEOTRACES research projects.



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Funding

Funding SourceAward
NSF Division of Ocean Sciences (NSF OCE)
NSF Division of Ocean Sciences (NSF OCE)

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