Contributors | Affiliation | Role |
---|---|---|
Jenkins, William J. | Woods Hole Oceanographic Institution (WHOI) | Principal Investigator, Contact |
Boyle, Edward A. | Massachusetts Institute of Technology (MIT) | Co-Principal Investigator |
Cutter, Gregory A. | Old Dominion University (ODU) | Co-Principal Investigator |
Gegg, Stephen R. | Woods Hole Oceanographic Institution (WHOI BCO-DMO) | BCO-DMO Data Manager |
CTD bottle data from 30-ODF/SIOR (Ocean Data Facility 12 bottle, 30 liter Niskin rosette) GT10 Transect.
"Filtered samples for non-contamination prone elements were collected from the ODF Niskin rosette (12 x 30L Niskin bottles) using AcroPak 500 filter cartridges with a Supor 0.45/0.8μm membrane attached to Teflon-lined Tygon tubing." (from KN199-04 cruise report). Refer to th KN199-04 Cruise Report for detailed descriptions of acquisition and processing methodologies.
Refer to th KN199-04 Cruise Report for detailed descriptions of acquisition and processing methodologies.
Note: 'FLAG_W' columns = WHP (WOCE Hydrographic Program) quality flags.
Processing Notes:
13 Feb 2013: BCO-DMO corrected the event numbers of several CTD casts. The correct event numbers were verified in the original cast sheets. Edits made:
Changed event number of station 2 cast 1 from 2022 to 2042;
Changed event number of station 4 cast 1 from 2024 to 2072;
Changed event number of station 5 cast 4 from 2075 to 2091;
Changed event number of station 7 cast 6 from 2107 to 2132;
Changed event number of station 9 cast 1 from 2009 to 2162;
Changed event number of station 9 cast 3 from 2059 to 2165.
The restriction on this dataset was removed according to instructions from the Chief Scientist, April 26, 2013.
File |
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CTD_ODF_Bottle_GT10.csv (Comma Separated Values (.csv), 298.79 KB) MD5:833243cd24f03e42ec7d02bcde781789 Primary data file for dataset ID 3519 |
Parameter | Description | Units |
EXPOCODE | Expedition code assigned by the CCHDO: NODCShipCodeYearMonthDay | text |
SECT_ID | Synonym for cruise. | text |
STNNBR | Station number. | integer |
CASTNO | Cast number. | integer |
GEOTRC_EVENTNO | GEOTRACES Event Number. | integer |
DATE | Date (UTC). in the format YYYYMMDD | unitless |
TIME | Time (UTC). in the format HHMM | unitless |
LATITUDE | Latitude (South is negative). | decimal degrees |
LONGITUDE | Longitude (West is negative). | decimal degrees |
GEOTRC_SAMPNO | GEOTRACES sample number. | integer |
SAMPNO | Sample number. | integer |
BTLNBR | Bottle identification number. | text |
BTLNBR_FLAT_W | Bottle quality flag. | integer |
BTO_DATE | Bottle sampling date. in the format YYYYMMDD | unitless |
BTL_TIME | Bottle collection time. in the format HHMM | unitless |
BTL_LAT | Bottle latitude (South is negative). | decimal degrees |
BTL_LON | Bottle longitude (West is negative). | decimal degrees |
BTMDEPTH | Bottom depth. | meters, corrected |
CTDPRS | CTD pressure. | decibars |
CTDDEPTH | CTD depth. | meters |
CTDTMP | CTD temperature. | ITS-90 |
CTDSAL | CTD salinity. | PSS-78 |
CTDSAL_FLAG_W | Quality flag for CTDSAL. | integer |
SALNTY | Bottle salinity. | PSS-78 |
SALNTY_FLAG_W | Quality flag for SALINITY. | integer |
CTDOXY | CTD Oxygen in micromoles per kilogram. | umol/kg |
CTDOXY_FLAG_W | Quality flag for CTDOXY. | integer |
OXYGEN | Bottle oxygen measured in micromoles per kilogram. | umol/kg |
OXYGEN_FLAG_W | OXYGEN FLAG W | integer |
SILCAT | Silicate. | umol/kg |
SILCAT_FLAG_W | Quality flag for SILCAT. | integer |
NITRAT | Nitrate. | umol/kg |
NITRAT_FLAG_W | Quality flag for NITRAT. | integer |
NITRIT | Nitirite. | umol/kg |
NITRIT_FLAG_W | Quality flag for NITRIT. | integer |
PHSPHT | Phosphate. | umol/kg |
PHSPHT_FLAG_W | Quality flag for PHSPHT. | integer |
REFTEMP | REFTEMP | ITS-90 |
REFTEMP_FLAG_W | REFTEMP FLAG W | integer |
CFC_11 | CFC 11 (trichlorofluoromethane) in picomoles per kilogram. | pmol/kg |
CFC_11_FLAG_W | Quality flag for CFC_11. | integer |
CFC_12 | CFC 12 (Dichlorodifluoromethane) in picomoles per kilogram. | pmol/kg |
CFC_12_FLAG_W | Quality flag for CFC_12. | integer |
CFC113 | CFC-113 (Trichlorotrifluoroethane) in picomoles per kilogram. | pmol/kg |
CFC113_FLAG_W | Quality flag for CFC113. | integer |
SF6 | SF6 (Sulfur hexafluoride) in fmol per kilogram. | fmol/kg |
SF6_FLAG_W | Quality flag for SF6. | integer |
TCARBN_M | TCARBN M | UMOL/KG |
TCARBN_M_FLAG_W | TCARBN M FLAG W | integer |
ALKALI_M | ALKALI M | UMOL/KG |
ALKALI_M_FLAG_W | ALKALI M FLAG W | integer |
TCARBN_B | TCARBN B | UMOL/KG |
TCARBN_B_FLAG_W | TCARBN B FLAG W | integer |
ALKALI_B | ALKALI B | UMOL/KG |
ALKALI_B_FLAG_W | ALKALI B FLAG W | integer |
TRITUM | Tritium. | TU |
TRITUM_FLAG_W | Quality flag for TRITUM. | integer |
HELIUM | Helium. | nmol/kg |
HELIUM_FLAG_W | Quality flag for HELIUM. | integer |
DELHE3 | Helium isotope ratio anomaly (percentage). | % |
DELHE3_FLAG_W | Quality flag for DELHE3. | integer |
DELC13 | DELC13 | /MILLE |
DELC13_FLAG_W | Quality flag for DELC13. | integer |
DELC14 | DELC14 | /MILLE |
DELC14_FLAG_W | Quality flag for DELC14. | integer |
D15N_NO3 | D15N NO3 | /MILLEvsAIR |
D15N_NO3_FLAG_W | D15N NO3 FLAG W | integer |
D18O_NO3 | D18O NO3 | /MILLEvsVSMOW |
D18O_NO3_FLAG_W | D18O NO3 FLAG W | integer |
O18_H2O | 18O H2O | /MILLE |
O18_H2O_FLAG_W | 18O H2O FLAG W | integer |
SI_SW_DISS | SI SW DISS | /MILLE |
SI_SW_DISS_FLAG_W | SI SW DISS FLAG W | integer |
SI_PM | SI PM | /MILLE |
SI_PM_FLAG_W | SI PM FLAG W | integer |
TCHLA | TCHLA | UG/L |
TCHLA_FLAG_W | TCHLA FLAG W | integer |
ACDOM | ACDOM | 1/M |
ACDOM_FLAG_W | ACDOM FLAG W | integer |
AP | AP | 1/M^2 |
AP_FLAG_W | AP FLAG W | integer |
DOC | Dissolved Organic Carbon in micromoles per liter. | UMOL/L |
DOC_FLAG_W | Quality flag for DOC. | integer |
POC | Particulate Organic Carbon in micrograms per liter. | ug/L |
POC_FLAG_W | Quality flag for POC. | integer |
SPM | SPM | UG/L |
SPM_FLAG_W | SPM FLAG W | integer |
HPLC_PIGMENTS | HPLC PIGMENTS | UG/L |
HPLC_PIGMENTS_FLAG_W | HPLC PIGMENTS FLAG W | integer |
CYSTEINE | CYSTEINE | PMOL/L |
CYSTEINE_FLAG_W | CYSTEINE FLAG W | integer |
GLUTATHIONE | GLUTATHIONE | PMOL/L |
GLUTATHIONE_FLAG_W | GLUTATHIONE FLAG W | integer |
GAMMA_GLU_CYST | GAMMA GLU CYST | PMOL/L |
GAMMA_GLU_CYST_FLAG_W | GAMMA GLU CYST FLAG W | integer |
HOMOCYSTEINE | HOMOCYSTEINE | PMOL/L |
HOMOCYSTEINE_FLAG_W | HOMOCYSTEINE FLAG W | integer |
PHYTOCHELATINS | PHYTOCHELATINS | PMOL/L |
PHYTOCHELATINS_FLAG_W | PHYTOCHELATINS FLAG W | integer |
METALLOTHEIONINE | METALLOTHEIONINE | PMOL/L |
METALLOTHEIONINE_FLAG_W | METALLOTHEIONINE FLAG W | integer |
DNA_CHISHOLM | DNA CHISHOLM | TBA |
DNA_CHISHOLM_FLAG_W | DNA CHISHOLM FLAG W | integer |
DNA_LAROCHE | DNA LAROCHE | TBA |
DNA_LAROCHE_FLAG_W | DNA LAROCHE FLAG W | integer |
BA | BA | NMOL/L |
BA_FLAG_W | BA FLAG W | integer |
ND_143_to_ND_144 | ND-143/ND-144 | RATIO |
ND_143_to_ND_144_FLAG_W | ND-143/ND-144 FLAG W | integer |
EPSILON_ND | EPSILON ND | (tbd) |
EPSILON_ND_FLAG_W | EPSILON ND FLAG W | integer |
PO_210 | PO 210 | DPM/100L |
PO_210_FLAG_W | PO 210 FLAG W | integer |
PB_210 | Pb-210 (Lead-210). | DPM/100L |
PB_210_FLAG_W | Quality flag for PB_210. | integer |
RA_226 | Radium-226 disintegrations per minute per 100 liters. | DPM/100L |
RA_226_FLAG_W | Quality flag for RA_226. | integer |
TH_230 | Thorium-230. | fg/kg |
TH_230_FLAG_W | Quality flag for TH_230. | integer |
TH_232 | Thorium-232. | pg/kg |
TH_232_FLAG_W | Quality flag for TH_232. | integer |
TH_232_COLLOIDS | TH 232 COLLOIDS | PG/KG |
TH_232_COLLOIDS_FLAG_W | TH 232 COLLOIDS FLAG W | integer |
TH_234 | Thorium-234. | DPM/L |
TH_234_FLAG_W | Quality flag for Th_234. | integer |
PA_231 | PA 231 | FG/KG |
PA_231_FLAG_W | PA 231 FLAG W | integer |
U_238 | Uranium-238. | TBA |
U_238_FLAG_W | Quality flag for U_238. | integer |
CS_137 | Caesium-137 in becquerels per cubic meter. | BQ/M^3 |
CS_137_FLAG_W | Quality flag for CS_137. | integer |
NP_237 | Neptunium-237. | MBQ/M^3 |
NP_237_FLAG_W | Quality flag for NP_237. | integer |
PU_239 | Plutonium-239. | MBQ/M^3 |
PU_239_FLAG_W | Quality flag for PU_239. | integer |
PU_240 | Plutonium-240. | MBQ/M^3 |
PU_240_FLAG_W | Quality flag for PU_240. | integer |
PU_240_to_PU_239 | PU-240/PU-239 | RATIO |
PU_240_to_PU_239_FLAG_W | PU-240/PU-239 FLAG W | integer |
REE_LA_UH | REE (Rare Earth Element) Lanthanum reported by University of Hawaii. | PMOL/KG |
REE_LA_UH_FLAG_W | Quality flag for REE_LA_UH. | integer |
REE_CE_UH | REE (Rare Earth Element) Cerium reported by University of Hawaii. | PMOL/KG |
REE_CE_UH_FLAG_W | Quality flag for REE_CE_UH. | integer |
REE_PR_UH | REE (Rare Earth Element) Praseodymium reported by University of Hawaii. | PMOL/KG |
REE_PR_UH_FLAG_W | Quality flag for REE_PR_UH. | integer |
REE_ND_UH | REE (Rare Earth Element) Neodymium reported by University of Hawaii. | PMOL/KG |
REE_ND_UH_FLAG_W | Quality flag for REE_ND_UH. | integer |
REE_PM_UH | REE (Rare Earth Element) Promethium reported by University of Hawaii. | PMOL/KG |
REE_PM_UH_FLAG_W | Quality flag for REE_PM_UH. | integer |
REE_SM_UH | REE (Rare Earth Element) Samarium reported by University of Hawaii. | PMOL/KG |
REE_SM_UH_FLAG_W | Quality flag for REE_SM_UH. | integer |
REE_EU_UH | REE (Rare Earth Element) Europium reported by University of Hawaii. | PMOL/KG |
REE_EU_UH_FLAG_W | Quality flag for REE_EU_UH. | integer |
REE_GD_UH | REE (Rare Earth Element) Gadolinium reported by University of Hawaii. | PMOL/KG |
REE_GD_UH_FLAG_W | Quality flag for REE_GD_UH. | integer |
REE_TB_UH | REE (Rare Earth Element) Terbium reported by University of Hawaii. | PMOL/KG |
REE_TB_UH_FLAG_W | Quality flag for REE_TB_UH. | integer |
REE_DY_UH | REE (Rare Earth Element) Dysprosium reported by University of Hawaii. | PMOL/KG |
REE_DY_UH_FLAG_W | Quality flag for REE_DY_UH. | integer |
REE_HO_UH | REE (Rare Earth Element) Holmium reported by University of Hawaii. | PMOL/KG |
REE_HO_UH_FLAG_W | Quality flag for REE_HO_UH. | integer |
REE_ER_UH | REE (Rare Earth Element) Erbium reported by University of Hawaii. | PMOL/KG |
REE_ER_UH_FLAG_W | Quality flag for REE_ER_UH. | integer |
REE_TM_UH | REE (Rare Earth Element) Thulium reported by University of Hawaii. | PMOL/KG |
REE_TM_UH_FLAG_W | Quality flag for REE_TM_UH. | integer |
REE_YB_UH | REE (Rare Earth Elements) Ytterbium reported by University of Hawaii. | PMOL/KG |
REE_YB_UH_FLAG_W | Quality flag for REE_YB_UH. | integer |
REE_LU_UH | REE (Rare Earth Element) Lutetium reported by University of Hawaii. | PMOL/KG |
REE_LU_UH_FLAG_W | Quality flag for REE_LU_UH. | integer |
Dataset-specific Instrument Name | GO-FLO Bottle |
Generic Instrument Name | GO-FLO Bottle |
Generic Instrument Description | GO-FLO bottle cast used to collect water samples for pigment, nutrient, plankton, etc. The GO-FLO sampling bottle is specially designed to avoid sample contamination at the surface, internal spring contamination, loss of sample on deck (internal seals), and exchange of water from different depths. |
Dataset-specific Instrument Name | Niskin bottle |
Generic Instrument Name | Niskin bottle |
Generic Instrument Description | A Niskin bottle (a next generation water sampler based on the Nansen bottle) is a cylindrical, non-metallic water collection device with stoppers at both ends. The bottles can be attached individually on a hydrowire or deployed in 12, 24, or 36 bottle Rosette systems mounted on a frame and combined with a CTD. Niskin bottles are used to collect discrete water samples for a range of measurements including pigments, nutrients, plankton, etc. |
Website | |
Platform | R/V Knorr |
Report | |
Start Date | 2010-10-15 |
End Date | 2010-11-04 |
Description | This cruise constitutes the first survey section as part of the U.S. participation in an international program named GEOTRACES.
Funding: NSF OCE award 0926423
Science Objectives: To obtain state of the art trace metal and isotope measurements on a suite of samples taken on a mid-latitude zonal transect of the North Atlantic. In particular, sampling targeted the oxygen minimum zone extending off the west African coast near Mauritania, the TAG hydrothermal field, and the western boundary current system along Line W. For additional information, please refer to the GEOTRACES program Web site (https://www.geotraces.org/) for overall program objectives and a summary of properties measured.
Science Activities include seawater sampling via GoFLO and Niskin carousels, in situ pumping (and filtration), CTDO2 and transmissometer sensors, underway pumped sampling of surface waters, and collection of aerosols and rain. Hydrography, CTD and nutrient measurements were supported by the Ocean Data Facility (J. Swift) at Scripps Institution of Oceanography and funded through NSF Facilities. They provided an additional CTD rosette system along with nephelometer and LADCP. A trace metal clean Go-Flo Rosette and winch were provided by the group at Old Dominion University (G. Cutter) along with a towed underway pumping system.
Additional cruise information is available from the Rolling Deck to Repository (R2R): https://www.rvdata.us/search/cruise/KN199-04
Other Relevant Links:
List of cruise participants: [ PDF ]
Cruise track: JPEG image (from Woods Hole Oceanographic Institution, vessel operator)
ADCP data are available from the Currents ADCP group at the University of Hawaii: KN199-04 ADCP |
Much of this text appeared in an article published in OCB News, October 2008, by the OCB Project Office.
The first U.S. GEOTRACES Atlantic Section will be specifically centered around a sampling cruise to be carried out in the North Atlantic in 2010. Ed Boyle (MIT) and Bill Jenkins (WHOI) organized a three-day planning workshop that was held September 22-24, 2008 at the Woods Hole Oceanographic Institution. The main goal of the workshop, sponsored by the National Science Foundation and the U.S. GEOTRACES Scientific Steering Committee, was to design the implementation plan for the first U.S. GEOTRACES Atlantic Section. The primary cruise design motivation was to improve knowledge of the sources, sinks and internal cycling of Trace Elements and their Isotopes (TEIs) by studying their distributions along a section in the North Atlantic (Figure 1). The North Atlantic has the full suite of processes that affect TEIs, including strong meridional advection, boundary scavenging and source effects, aeolian deposition, and the salty Mediterranean Outflow. The North Atlantic is particularly important as it lies at the "origin" of the global Meridional Overturning Circulation.
It is well understood that many trace metals play important roles in biogeochemical processes and the carbon cycle, yet very little is known about their large-scale distributions and the regional scale processes that affect them. Recent advances in sampling and analytical techniques, along with advances in our understanding of their roles in enzymatic and catalytic processes in the open ocean provide a natural opportunity to make substantial advances in our understanding of these important elements. Moreover, we are motivated by the prospect of global change and the need to understand the present and future workings of the ocean's biogeochemistry. The GEOTRACES strategy is to measure a broad suite of TEIs to constrain the critical biogeochemical processes that influence their distributions. In addition to these "exotic" substances, more traditional properties, including macronutrients (at micromolar and nanomolar levels), CTD, bio-optical parameters, and carbon system characteristics will be measured. The cruise starts at Line W, a repeat hydrographic section southeast of Cape Cod, extends to Bermuda and subsequently through the North Atlantic oligotrophic subtropical gyre, then transects into the African coast in the northern limb of the coastal upwelling region. From there, the cruise goes northward into the Mediterranean outflow. The station locations shown on the map are for the "fulldepth TEI" stations, and constitute approximately half of the stations to be ultimately occupied.
Figure 1. The proposed 2010 Atlantic GEOTRACES cruise track plotted on dissolved oxygen at 400 m depth. Data from the World Ocean Atlas (Levitus et al., 2005) were plotted using Ocean Data View (courtesy Reiner Schlitzer). [click on the image to view a larger version]
Hydrography, CTD and nutrient measurements will be supported by the Ocean Data Facility (J. Swift) at Scripps Institution of Oceanography and funded through NSF Facilities. They will be providing an additional CTD rosette system along with nephelometer and LADCP. A trace metal clean Go-Flo Rosette and winch will be provided by the group at Old Dominion University (G. Cutter) along with a towed underway pumping system.
The North Atlantic Transect cruise began in 2010 with KN199 leg 4 (station sampling) and leg 5 (underway sampling only) (Figure 2).
Figure 2. The red line shows the cruise track for the first leg of the US Geotraces North Atlantic Transect on the R/V Knorr in October 2010. The rest of the stations (beginning with 13) will be completed in October-December 2011 on the R/V Knorr (courtesy of Bill Jenkins, Chief Scientist, GNAT first leg). [click on the image to view a larger version]
The section completion effort resumed again in November 2011 with KN204-01A,B (Figure 3).
KN204-01A,B Cruise Report (PDF)
Figure 3. Station locations occupied on the US Geotraces North Atlantic Transect on the R/V Knorr in November 2011. [click on the image to view a larger version]
Data from the North Atlantic Transect cruises are available under the Datasets heading below, and consensus values for the SAFe and North Atlantic GEOTRACES Reference Seawater Samples are available from the GEOTRACES Program Office: Standards and Reference Materials
ADCP data are available from the Currents ADCP group at the University of Hawaii at the links below:
KN199-04 (leg 1 of 2010 cruise; Lisbon to Cape Verde)
KN199-05 (leg 2 of 2010 cruise; Cape Verde to Charleston, NC)
KN204-01A (part 1 of 2011 cruise; Woods Hole, MA to Bermuda)
KN204-01B (part 2 of 2011 cruise; Bermuda to Cape Verde)
GEOTRACES is a SCOR sponsored program; and funding for program infrastructure development is provided by the U.S. National Science Foundation.
GEOTRACES gained momentum following a special symposium, S02: Biogeochemical cycling of trace elements and isotopes in the ocean and applications to constrain contemporary marine processes (GEOSECS II), at a 2003 Goldschmidt meeting convened in Japan. The GEOSECS II acronym referred to the Geochemical Ocean Section Studies To determine full water column distributions of selected trace elements and isotopes, including their concentration, chemical speciation, and physical form, along a sufficient number of sections in each ocean basin to establish the principal relationships between these distributions and with more traditional hydrographic parameters;
* To evaluate the sources, sinks, and internal cycling of these species and thereby characterize more completely the physical, chemical and biological processes regulating their distributions, and the sensitivity of these processes to global change; and
* To understand the processes that control the concentrations of geochemical species used for proxies of the past environment, both in the water column and in the substrates that reflect the water column.
GEOTRACES will be global in scope, consisting of ocean sections complemented by regional process studies. Sections and process studies will combine fieldwork, laboratory experiments and modelling. Beyond realizing the scientific objectives identified above, a natural outcome of this work will be to build a community of marine scientists who understand the processes regulating trace element cycles sufficiently well to exploit this knowledge reliably in future interdisciplinary studies.
Expand "Projects" below for information about and data resulting from individual US GEOTRACES research projects.
Funding Source | Award |
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NSF Division of Ocean Sciences (NSF OCE) | |
NSF Division of Ocean Sciences (NSF OCE) |