Methodology: basic hydrographic data; thorium-234, please see published
references: Buesseler at al. 2001 and Pike et al. 2005
Buesseler, K. O., C. Benitez-Nelson, Rutgers van der Loeff, M., Andrews,
J., Ball, L., Crossin, G., and M. Charette (2001). An intercomparison of
small- and large-volume techniques for thorium-234 in seawater. Marine Chemistry, 74, 15-28. (PDF)
Pike, S.M., K.O. Buesseler, J. Andrews and N. Savoye (2005). Quantification
of 234Th recovery in small volume sea water samples by inductively coupled
plasma mass spectrometry. Journal of Radioanalytical and Nuclear Chemistry, 263(2): 355-360. (PDF)
Change history: YYMMDD
060123: Added by Cyndy Chandler (cchandler@whoi.edu), OCB CDMO; basic
hydrographic data from Niskin bottles contributed by Dave Siegel
060905: remove O2, T, C and derived params from station 20 per Chief Scientist request;
sensor caps left on during deployment
080707: niskin data updated with nutrient and HPLC pigment data from
Ken Buesseler
081202: uncalibrated PAR and derived fucox/chla_total ratio removed
081208: fluorometric chlorophyll a contributed by Sei-ichi Saitoh
DMO note: Thorium 234 data from Niskin bottle samples are available for
VERTIGO participants (restricted access).
event, date, time, latitude and longitude are from the CTD cast
NMEA header lines; T_local (local time at study area) was computed
by adjusting GMT time by +11
As of January 2006, oxygen, fluorescence, turbidity, transmissivity
and PAR had not yet been compared with in-situ data and should
be used by others with caution until finalized.
PIC sensor: voltage 0 - 5: WET Labs PIC 001 (4th build)
POC sensor: voltage 0 - 5: WET Labs CST-DR 391 - tranmsissometer
scattering sensor: voltage 0 - 5: Seapoint scattering sensor
Fluorometric chlorophyll-a data (acquired using standard Turner method)
were contributed by Se-ichi Saitoh (Hokkaido Univ., Japan) with target
(nominal) depths but no Niskin bottle numbers. DMO staff were able to
determine most of the Niskin bottle numbers by checking the chl-a
sampling records as entered on the origninal sample log sheets.
Exceptions and comments are noted below:
cast bot depth_n chl_a comments
6 12 5 0.29 bottles 12 and 14
6 3 200 0.01 originally reported as cast 8
18 21 5 0.44 bottles 21 and 24
28 12 10 0.50 bottle 12 is a guess for 10 m sample
31 21 5 0.35 bottles 21 and 24
36 12 10 0.42 bottle 12 is a guess for 10 m sample
39 22 5 0.33 bottles 22 and 24
62 21 5 0.30 bottles 21 and 24
and for many casts, according to original paper sample log sheets:
deepest chl-a sample noted was at 50 m
(e.g. deeper samples reported in data file not recorded on sample log sheet)
casts 23 and 76
sample log sheet noted that sample also taken from bottle 24 at <5 m
(but no Turner flourometric chl-a data reported from <5m)
casts 28 and 36
no Turner flourometric chl-a samples reported on log sheet
but chl-a data were reported for Turner flourometric method
PI note: HPLC data are concentrations in ng/L, based on 2 L filtration volume;
The -9 values for prasinoxanthin do not indicate zero concentration,
but rather inability to quantify (it was co-eluting with another peak).